Abstract: | In the title supramolecular complex, [Ag2Cl2(C4H5N3)(C18H15P)2]n, a one‐dimensional chain is formed by dimeric {Ag2Cl2(PPh3)2} units bridged by 2‐aminopyrimidine moieties. The Ag atoms are four‐coordinate, with an AgCl2NP core. A crystallographic inversion centre is located in the centre of the Ag2Cl2 chelate ring, while the crystallographic twofold axis bisects the 2‐aminopyrimidine ligand. |