catena‐Poly[[di‐μ‐chloro‐bis[(triphenylphosphine)silver(I)]]‐μ‐2‐aminopyrimidine‐κ2N1:N3]

In the title supramolecular complex, Ag₂Cl₂(C₄H₅N₃)(C₁₈H₁₅P)₂]_n, a one‐dimensional chain is formed by dimeric {Ag₂Cl₂(PPh₃)₂} units bridged by 2‐amino­pyrimidine moieties. The Ag atoms are four‐coordinate, with an AgCl₂NP core. A crystallographic inversion centre is located in the centre of the Ag₂Cl₂ chelate ring, while the crystallographic twofold axis bisects the 2‐amino­pyrimidine ligand.