μ‐Cyano‐1:2κ2C:N‐tetracyano‐1κ4C‐(5‐methyl‐5‐nitro‐3,7‐diazanonane‐1,9‐diamine‐2κ4N1,3,7,9)‐nitrosyl‐1κN‐copper(II)iron(II) dihydrate |
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Authors: | Liang Shen Yi‐Jian Zhang Guo‐Ding Sheng Hua‐Tong Wang |
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Abstract: | The title binuclear complex, CuFe(CN)5(C8H21N5O2)(NO)]·2H2O or CuFe(nelin)(CN)5(NO)]·2H2O (nelin is 5‐methyl‐5‐nitro‐3,7‐diazanonane‐1,9‐diamine) consists of discrete binuclear mixed‐metal species, with a Cu centre linked to an Fe centre through a cyano bridge, and two water molecules of crystallization. In the complex, the CuII ion is coordinated by five N atoms and has a distorted square‐pyramidal geometry. The FeII centre is in a distorted octahedral environment. |
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