Abstract: | In the structure of the title compound, 4‐[3‐carboxy‐6,8‐difluoro‐1‐(2‐fluoroethyl)‐1,4‐dihydro‐4‐oxo‐7‐quinolyl]‐1‐methylpiperazinium chloride hydrate, C17H19F3N3O3+·Cl?·H2O, the quinoline and its substituents, except for the fluoroethyl group, are coplanar, while the piperazinium moiety exists in a chair form. There are π–π‐stacking interactions between the quinoline rings, and intra‐ and intermolecular hydrogen bonds in the crystal. |