trans‐Diacetonitrilebis(di‐2‐pyridyl sulfide‐N,N′)ruthenium(II) bis(tetrafluoroborate) monohydrate |
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| Authors: | Giuseppe Bruno Francesco Nicol Giuseppe Tresoldi Santo Lanza |
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| Institution: | Giuseppe Bruno,Francesco Nicoló,Giuseppe Tresoldi,Santo Lanza |
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| Abstract: | The title complex, Ru(C10H8N2S)2(CH3CN)2](BF4)2·H2O, is the product of the solvolysis of Ru(dps‐N,N)2(dps‐N,S)](PF6)2 (dps is di‐2‐pyridyl sulfide) in the presence of HBF4 in acetone–acetonitrile at room temperature. There are two independent cations, with the Ru atoms on inversion centres; each Ru atom has an octahedral geometry with the dps molecules behaving as N,N′‐bidentate ligands and assuming a trans arrangement. |
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