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Polypropylene/talc composites modified by a succinyl‐fluorescein grafted atactic polypropylene: A thermal and mechanical study under dynamic conditions
Authors:J Ma García‐Martínez  O Laguna  S Areso  E P Collar
Abstract:This article reports on the interfacial modifications induced by different amounts of a succinyl‐fluorescein grafted atactic polypropylene (a‐PP‐SF) as a truly interfacial agent in polypropylene/talc composite materials. The a‐PP‐SF used, which contains 4% grafts, was previously obtained in our laboratory by chemical modification of a byproduct from industrial polymerization reactors. Thermal and mechanical analyses of composites, performed under dynamic conditions, led to the correlation of parameters at the microscopic scale with others at the macroscopic scale. Thus, the interfacial effect caused by different amounts of a‐PP‐SF in the composite can be concluded by observations made at either scale. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1371–1382, 2002
Keywords:composites  crystallization  DSC  functionalization of polymers  interfaces  polyolefins  mechanical properties  viscoelastic properties
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