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catena‐Poly­[[tri‐n‐butyl­tin]‐μ‐N‐(1‐naphthyl)­maleamato]
Authors:Masood Parvez  Saqib Ali  Sajjad Ahmad  Moazzam Hussain Bhatti  Muhammad Mazhar
Abstract:The crystal structure of catena‐poly­tri‐n‐butyl­tin]‐μ‐3‐(1‐naph­thyl­amino­carbonyl)­acrylato‐κ2O1:O3], Sn(C4H9)3(C14H10NO3)]n, is composed of polymeric chains wherein the metal center exhibits a distorted trigonal‐bipyramidal geometry, with three n‐butyl groups defining the trigonal plane mean Sn—C 2.133 (7) Å] and the axial positions being occupied by the carboxyl­ate O atoms of two different N‐(1‐naphthyl)­maleamate ligands with inequivalent Sn—O distances 2.167 (4) and 2.457 (4) Å]. The N‐(1‐naphthyl)­maleamate fragment forms an essentially planar seven‐membered ring involving an intramolecular N—H?O hydrogen bond.
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