Hydrogen‐bonded supramolecular lattice of the 1:3:4 complex between [5,10,15,20‐meso‐tetrakis(4‐hydroxyphenyl)porphyrinato‐κ4N]zinc(II), dibenzo‐24‐crown‐8 and methanol |
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Authors: | Yael Diskin‐Posner Goutam Kumar Patra Israel Goldberg |
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Abstract: | The title compound, [5,10,15,20‐meso‐tetrakis(4‐hydroxyphenyl)porphyrinato‐κ4N]zinc(II) tris(dibenzo‐24‐crown‐8) methanol tetrasolvate, [Zn(C44H28N4O4)]·3C24H32O8·4CH4O, was synthesized and its molecular structure precisely characterized by low‐temperature single‐crystal analysis. All the components are involved in hydrogen bonding with each other, thus forming an extensively hydrogen‐bonded supramolecular lattice. The functionalized porphyrin moiety coordinates both equatorially and axially to the neighboring species. |
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