Bis(isoquinoline‐1‐carboxylato‐κ2O,N)(1,10‐phenanthroline‐κ2N,N′)zinc(II) dimethylformamide sesquisolvate |
| |
Authors: | Jean‐Claude Daran Pascale Lemoine Bernard Viossat |
| |
Abstract: | The asymmetric unit of the title compound, [Zn(C10H6NO2)2(C12H8N2)]·1.5C3H7NO, contains one monomeric zinc complex and 1.5 disordered dimethylformamide solvate molecules. The Zn atom is coordinated to one 1,10‐phenanthroline ligand and to two isoquinolinecarboxylate anions (IQC?) via their N and O atoms. The complex exhibits a distorted octahedral geometry around the ZnII atom, with the apical positions occupied by the O atoms of the IQC? ligands. The Zn atom lies 0.049 (1) Å out of the basal plane. The crystal packing is characterized by several hydrogen bonds. |
| |
Keywords: | |
|
|