Abstract: | Alternating C6H14N22+ and BeF4]2? units within the ac plane of 1,4‐diazoniabicyclo2.2.2]octane tetrafluoroberyllium hemihydrate, (C6H14N2)BeF4]·0.5H2O, combine to form double chains via hydrogen bonding. These double chains connect through bifurcated hydrogen bonds to water molecules, which lie on twofold axes, producing a two‐dimensional sheet. Very weak hydrogen‐bond interactions, along the b axis, join the sheets to produce a three‐dimensional network. |