首页 | 本学科首页   官方微博 | 高级检索  
     检索      


trans‐Bis­[1‐methyl‐3‐(p‐nitro­phenyl)­triazenido 1‐oxide‐κ2N3,O]­di­pyridine­nickel(II)
Authors:Manfredo Hrner  Julieta Saldanha de Oliveira  Jairo Bordinhao  Johannes Beck
Institution:Manfredo Hörner,Julieta Saldanha de Oliveira,Jairo Bordinhao,Johannes Beck
Abstract:In the centrosymmetric title complex, Ni(C7H7N4O3)2(C5H5N)2], the coordination geometry about the Ni2+ ion is octahedral, with two deprotonated 1‐methyl‐3‐(p‐nitro­phenyl)­triazenide 1‐oxide ions, viz. O2N­C6H4­NNN(O)­CH3]?, acting as bidentate ligands (four‐electron donors). Two neutral pyridine (py) mol­ecules complete the coordination sphere in positions trans to each other. The triazenide 1‐oxide ligand is almost planar, the largest interplanar angle of 8.80 (12)° being between the phenyl ring of the p‐nitro­phenyl group and the plane defined by the N3O moiety. The Ni—Ntriazenide, Ni—O and Ni—Npy distances are 2.0794 (16), 2.0427 (13) and 2.1652 (18) Å, respectively.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号