Bis[trans‐dibromo(2,2‐dimethylpropane‐1,3‐diamine‐κ2N,N′)chromium(III)] dibromide hydrogen perchlorate hexahydrate |
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Authors: | Jong‐Ha Choi Takayoshi Suzuki Sumio Kaizaki |
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Abstract: | In the title compound, CrBr2(C5H14N2)2]2Br2·HClO4·6H2O, there are two independent CrIII complex cations which are conformational isomers of each other. The Cr atoms lie respectively on a center of symmetry and on a mirror plane and have octahedral environments, coordinated by the N atoms of two 2,2‐dimethylpropane‐1,3‐diamine ligands and by two Br atoms in trans positions. The Cr—N and Cr—Br bond lengths are in the ranges 2.078 (3)–2.089 (3) and 2.4495 (9)–2.5017 (9) Å, respectively. The crystal structure consists of two CrIII complex cations, two Br? anions, a (ClO4)? anion and an H13O6]+ hydrogen‐bonded cluster cation. |
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