Bis[μ‐4‐(ethylammoniomethyl)‐3,5‐dimethylpyrazolato‐κ2N1:N2]bis[(η4‐1,5‐cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate |
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| Authors: | Glria Esquius Josefina Pons Ramn Yez Josep Ros Xavier Solans Merc Font‐Bardia |
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| Institution: | Glòria Esquius,Josefina Pons,Ramón Yáñez,Josep Ros,Xavier Solans,Mercè Font‐Bardia |
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| Abstract: | In the title compound, Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as μ‐bridges. The coordination of each RhI cation is completed by one cyclooctadiene (COD) ligand. It is shown that the average Rh—C(COD) distance is linearly dependent on the Rh—N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing. |
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