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()‐12‐Oxotri­cyclo­[6.2.2.01,6]­dodec­ane‐10‐carboxyl­ic acid: hydrogen bonding in a tricyclic δ‐keto acid
Authors:Markos M Papadakis  Sonia P Martins  Hugh W Thompson  Roger A Lalancette
Abstract:The ring system of the title compound, C13H18O3, was synthesized by addition of ethyl acryl­ate to the dien­amine of 2‐octalone. The keto acid aggregates in the solid as acid‐to‐acid dimers O?O = 2.663 (2) Å and O—H?O = 170 (3)°] whose centrosymmetric hydrogen bonds lie across the a edges and the center of the chosen cell. Three intermolecular C—H?O close contacts within 2.7 Å were found involving the ketone group.
Keywords:
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