The new thioantimonate(V) (C3H10N)[NiSbS4(C6H18N4)] |
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Authors: | Ralph St hler,Wolfgang Bensch |
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Affiliation: | Ralph Stähler,Wolfgang Bensch |
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Abstract: | Turquoise crystals of the title salt, propylammonium di‐μ‐thio‐1:2κ4S‐dithio‐2κ2S‐tris(2‐aminoethyl)amine‐1κ4N‐antimony(V)nickel(II), (C3H10N)[NiSbS4(C6H18N4)] or [PAH][Ni(tren)SbS4] [where tren is tris(2‐aminoethyl)amine and PA is propylamine], were synthesized under solvothermal conditions by reacting [Ni(tren)2]Cl2, Sb and S in a solution of PA. The NiII ion is octahedrally surrounded by four N atoms of the tetradentate tren molecule and by two S atoms of the tetrahedral [SbVS4]3? anion, thus forming the anionic [Ni(tren)SbS4]? part of the compound. Charge balance is achieved through the PAH+ cation. An extended intermolecular hydrogen‐bonding network is observed between the anion and the cation. |
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