Aquachloro(1,10‐phenanthroline‐κ2N,N′)(p‐toluenesulfonato‐κO)copper(II) |
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Authors: | Cristina Aller Jesús Castro Paulo Prez‐Lourido Elena Labisbal Jos Arturo García‐Vzquez |
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Institution: | Cristina Aller,Jesús Castro,Paulo Pérez‐Lourido,Elena Labisbal,José Arturo García‐Vázquez |
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Abstract: | In the title compound, CuCl(C7H7O3S)(C12H8N2)(H2O)], the central Cu atom is coordinated by a water molecule, a chloride ion, an O‐monodentate p‐toluenesulfonate anion and an N,N′‐bidentate 1,10‐phenanthroline ligand. The copper environment is best described as a slightly distorted square pyramid, with bond distances Cu—Cl 2.2282 (9) Å, Cu—OW 1.984 (3) Å, and Cu—N 2.006 (3) and 2.028 (3) Å; the apical Cu—O distance is 2.281 (2) Å. In the supramolecular structure, π–π‐stacking stabilization is observed, and classical and non‐classical hydrogen bonds also play an important role. |
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