Dichloro{N‐[3‐(η5‐cyclopentadienyl)propyl]‐4‐toluenesulfonamido‐κ2N,O}titanium(IV) |
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Authors: | Cornelis Lensink Graeme J. Gainsford Menno J. R. Brandsma |
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Abstract: | The title compound, [Ti(C15H17NO2S)Cl2], has a Ti atom bound to the N and O atoms of a p‐toluenesulfonamide ligand, which is tethered by a three‐carbon chain to a η5‐cyclopentadienyl group. The distorted square‐pyramidal geometry is completed by two Cl atoms. The Ti—N bond length of 2.0375 (13) Å is longer than that in related compounds, the N atom having asymmetric trigonal–planar geometry. Conformational strain relief is noted when compared with ethyl‐tethered compounds. |
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