cis‐[1,2‐Bis(diisopropylphosphino‐κP)‐1,2‐dicarba‐closo‐dodecaborane]dichloroplatinum(II) dichloromethane hemisolvate |
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Authors: | Sari Paavola Francesc Teixidor Clara Vias Raikko Kiveks |
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Institution: | Sari Paavola,Francesc Teixidor,Clara Viñas,Raikko Kivekäs |
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Abstract: | The asymmetric unit of the title complex, PtCl2(C14H38B10P2)]·0.5CH2Cl2 or cis‐PtCl2{1,2‐(PiPr2)2‐1,2‐C2B10H10}]·0.5CH2Cl2, contains one disordered solvent molecule and two molecules of the complex, in which each PtII atom displays slightly distorted square‐planar coordination geometry. The P atoms connected to the cage C atoms are coordinated to the PtII atom. The Pt—P distances vary slightly 2.215 (3) and 2.235 (4) Å] and the Pt—Cl distances are equal 2.348 (3) and 2.353 (5) Å]. |
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