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cis‐[1,2‐Bis(diisopropylphosphino‐κP)‐1,2‐dicarba‐closo‐dodecaborane]dichloroplatinum(II) dichloromethane hemisolvate
Authors:Sari Paavola  Francesc Teixidor  Clara Vias  Raikko Kiveks
Institution:Sari Paavola,Francesc Teixidor,Clara Viñas,Raikko Kivekäs
Abstract:The asymmetric unit of the title complex, PtCl2(C14H38B10P2)]·0.5CH2Cl2 or cis‐PtCl2{1,2‐(PiPr2)2‐1,2‐C2B10H10}]·0.5CH2Cl2, contains one disordered solvent mol­ecule and two mol­ecules of the complex, in which each PtII atom displays slightly distorted square‐planar coordination geometry. The P atoms connected to the cage C atoms are coordinated to the PtII atom. The Pt—P distances vary slightly 2.215 (3) and 2.235 (4) Å] and the Pt—Cl distances are equal 2.348 (3) and 2.353 (5) Å].
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