Abstract: | The title complex, {CdHg(SCN)4(C4H9NO)2]2}n, contains two crystallographically independent CdII centres and two HgII centres. Each CdII atom is bound to four N atoms belonging to SCN groups and to two O atoms from N,N‐dimethylacetamide (DMA) ligands in an octahedral geometry. Each HgII centre is tetrahedrally coordinated by four SCN S atoms. |