Hexaaquadodeca‐μ‐bromo‐octahedro‐hexatantalum bromide chloride octahydrate |
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Authors: | Marija Vojnovi ,Berislav Peri ,Pavica Planini ,Gerald Giester,Nevenka Brni
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Affiliation: | Marija Vojnović,Berislav Perić,Pavica Planinić,Gerald Giester,Nevenka Brničević |
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Abstract: | The title compound, [Ta6Br12(H2O)6](Br0.4Cl1.6)·8H2O, crystallizes in space group P. The structure contains two crystallographically independent [Ta6Br12(H2O)6]2+ cluster cations forming distinct layers parallel to the ab plane. The compound is isoconfigurational with the double salts [Ta6Br12(H2O)6]X2·trans‐[Ta6Br12(OH)4(H2O)2]·18H2O (X = Cl, Br). |
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