Über dimere dimethylmetall-bis(trimethylgermyl)amide des aluminiums, galliums und indiums |
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| Authors: | M Trapp H -D Hausen G Weckler J Weidlein |
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| Institution: | Institut für Anorganische Chemie der Universität Stuttgart Pfaffenwaldring 55, W- 7000 Stuttgart 80 Deutschland |
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| Abstract: | The dimethylmetal bis(trimethylgermyl)amides of Al, Ga, and In have been prepared from LiN(GeMe3)2] and Me2MCl (Me = CH3, M = Al, Ga) or Me2MCN (M = Ga, In) in inert solvents. The NMR (1H, 13C) and vibrational spectra (IR and Raman) of these dimeric compounds have been assigned and discussed. According to the X-ray structure determination Me2InN(GeMe3)2]2 crystallizes in the monoclinic space group C2/c (Z = 4, R = 0.032) and is isomorphous with the bis(trimethylsilyl) homologue. |
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