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Application of chiral lanthanide shift reagents for assignment of absolute configuration of alcohols
Authors:Ghosh Indranath  Zeng Hongbo  Kishi Yoshito
Affiliation:Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Abstract:[structure: see text] The absolute configuration of secondary and tertiary alcohols can be predicted from analysis of the chemical shift behaviors of the CX- and CY-carbons in the presence of (R)- and (S)-Pr(tfc)3 as formulated in the boxes.
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