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Derivatives of 1,4-diaryl-5,6,7,8-tetrahydro-2,2a,8a-triazacyclopenta[c,d]azulene
Authors:A. M. Demchenko
Affiliation:(1) Institution of the Russian Academy of Sciences, A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, Kazan, 420088, Russia
Abstract:Derivatives of the previously unknown heterocyclic system 2,2a,8a-triazacyclopenta[c,d] azulene were synthesized by condensation of 3-aryl-4,5-pentamethylene-1,2,4-triazoles or 2-(beta-aroylhydrazin)-l-aza-Delta-cycloheptene with agr-halogeno ketones, followed by cyclization of the intermediate products in alkaline media.T. G. Shevchenko Chernigov Pedagogical University, Chernigov 250037, Ukraine; e-mail: chspu@mail.cn.ua. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1123–1127, August, 2000.
Keywords:3-aryl-4,5-pentamethylene-1,2,4-triazoles    /content/p10523131705uh79/xxlarge945.gif"   alt="  agr"   align="  BASELINE"   BORDER="  0"  >-halogeno ketones  2,2a,8a-triazacyclopenta[c,d]-azulene  correlation dependence of proton chemical shifts  cyclization in alkaline media  quaternary phenacylium salts
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