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CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO-5- ETHYL-5-METHYL-3-PHENYL-1, 3, 4-DIAZAPHOSPHOLIDIN-2-THIONE-4-SULFIDE
引用本文:Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry,Nankai University,Tianjin 300071Wang Hong-Gen Wang Ru-JiCentral laboratory,Nankai University,Tianjin 300071. CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO-5- ETHYL-5-METHYL-3-PHENYL-1, 3, 4-DIAZAPHOSPHOLIDIN-2-THIONE-4-SULFIDE[J]. 结构化学, 1993, 0(5)
作者姓名:Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry  Nankai University  Tianjin 300071Wang Hong-Gen Wang Ru-JiCentral laboratory  Nankai University  Tianjin 300071
作者单位:Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry,Nankai University,Tianjin 300071Wang Hong-Gen Wang Ru-JiCentral laboratory,Nankai University,Tianjin 300071
摘    要:<正> Crystal of the title compound Mr=304. 80 belongs to the triclinic, space group P1, with a = 7. 282)2), b=9. 064(2), c=11. 737(5) A , α=75. 79 (3), β=78. 70(3), γ=88. 49(2)°, V-736. 21 A3, Z=2, Dx = l. 375 g/cm3. The final refinement is converged with R=0. 062 and Rw= 0. 069.The five-membered heterocycle is in envelope conformation. The P - N bond length (1. 68(1)) indicates that the dπ-Pπ bond between P and N of the title compound is stronger than that of the corresponding 4-phenyl compound.


CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO-5- ETHYL-5-METHYL-3-PHENYL-1, 3, 4-DIAZAPHOSPHOLIDIN-2-THIONE-4-SULFIDE
Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry,Nankai University,Tianjin Wang Hong-Gen Wang Ru-JiCentral laboratory,Nankai University,Tianjin. CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO-5- ETHYL-5-METHYL-3-PHENYL-1, 3, 4-DIAZAPHOSPHOLIDIN-2-THIONE-4-SULFIDE[J]. Chinese Journal of Structural Chemistry, 1993, 0(5)
Authors:Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry  Nankai University  Tianjin Wang Hong-Gen Wang Ru-JiCentral laboratory  Nankai University  Tianjin
Affiliation:Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry,Nankai University,Tianjin 300071Wang Hong-Gen Wang Ru-JiCentral laboratory,Nankai University,Tianjin 300071
Abstract:Crystal of the title compound Mr=304. 80 belongs to the triclinic, space group P1, with a = 7. 282)2), b=9. 064(2), c=11. 737(5) A , α=75. 79 (3), β=78. 70(3), γ=88. 49(2)°, V-736. 21 A3, Z=2, Dx = l. 375 g/cm3. The final refinement is converged with R=0. 062 and Rw= 0. 069.The five-membered heterocycle is in envelope conformation. The P - N bond length (1. 68(1)) indicates that the dπ-Pπ bond between P and N of the title compound is stronger than that of the corresponding 4-phenyl compound.
Keywords:Heterocycle Compound Crystal Structure
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