EPR study of the rearrangement of (C2H5)3SiCH2CH2ĊCl2 radicals |
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| Authors: | R. G. Gasanov N. V. Blinova |
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| Affiliation: | (1) A. N. Nesmeyanov Institute for Organometallic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions It has been established that the rearrangement of (C2H5)3Si(CH2)2 Cl2 radicals into (C2H5)2Si(CH3CH)(CH2)2CCl2H takes place by an intramolecular mechanism with 1,5-migration of a hydrogen atom. The rate constant for the isomerization has been determined at 20°C and found to be (2.2 ± 0.3)·103 sec–1.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2512–2516, November, 1988. |
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