Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle |
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| Authors: | Sessler Jonathan L Tomat Elisa Lynch Vincent M |
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| Affiliation: | Department of Chemistry and Biochemistry, The University of Texas at Austin, 78712-0165, USA. sessler@mail.utexas.edu |
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| Abstract: | The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect. |
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