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Eu(DBM)3超微粒子的光谱特性
引用本文:胡林学,王宝兰,李建平,李小琴,李洪彬. Eu(DBM)3超微粒子的光谱特性[J]. 物理化学学报, 1997, 13(1): 56-59. DOI: 10.3866/PKU.WHXB19970111
作者姓名:胡林学  王宝兰  李建平  李小琴  李洪彬
作者单位:Department of Chemistry,Laboratory Center,Hubei University,Wuhan 430062
摘    要:

关 键 词:超微粒子  Eu(DBM)3  荧光光谱  
收稿时间:1996-05-24
修稿时间:1996-08-19

Spectral Properties of Ultrafine Particles of Eu(DBM)_3
Hu Lin-Xue,Wang Bao-Lan,Li Jian-Ping,Li Xiao-Qin,Li Hong-Bin. Spectral Properties of Ultrafine Particles of Eu(DBM)_3[J]. Acta Physico-Chimica Sinica, 1997, 13(1): 56-59. DOI: 10.3866/PKU.WHXB19970111
Authors:Hu Lin-Xue  Wang Bao-Lan  Li Jian-Ping  Li Xiao-Qin  Li Hong-Bin
Affiliation:Department of Chemistry,Laboratory Center,Hubei University,Wuhan 430062
Abstract:The colloids of Eu(DBM)3 and ultrafine particles Eu(DBM)3 were perpared. The particle sizes determined by X-ray and by TEM measurements were in 7-30nm range. Their UV absorption and fluorescence spectra were compared with each other and with those of the solid sample. It was shown that the 5D1→7 F1,2 transition was observed in the colloids of Eu(DBM)3 at room temperature. The increase of the excited-state S1 and T1 energy, the peak positions of UV absorption shifted to shorter wavelength, the changes of the absoprtion coefficient with decreasing size were observed.
Keywords:Ultrafine particle   Eu(DBM)_3   Fluorescence spectra
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