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苯并三氮唑对18-8钢应力腐蚀开裂的缓蚀作用
引用本文:牛林,林海潮,曹楚南,宋光铃.苯并三氮唑对18-8钢应力腐蚀开裂的缓蚀作用[J].物理化学学报,1997,13(9):802-807.
作者姓名:牛林  林海潮  曹楚南  宋光铃
作者单位:Institute of Corrosion and Protection of Metals,State Key Laboratory for Corrosion and Protection,The Academy of Sciences,Sehnyang 110015
基金项目:国家自然科学基金,中国科学院“百人计划”资助
摘    要:利用慢应变速率技术(SSRT),并结合电化学极化曲线和阻抗实验方法研究了苯并三氮唑(BTA)添加剂对1Cr18Ni9Ti奥氏体不锈钢在0.5mol·L-1HCl+0.5mol·L-1NaCl溶液中应力腐蚀和均匀腐蚀的缓蚀作用.结果表明,这种添加剂的缓蚀作用主要是抑制腐蚀的阳极过程而产生的.

关 键 词:1Cr18Ni9Ti不锈钢  应力腐蚀开裂敏感性  缓蚀作用机理  吸附  阳极溶解  
收稿时间:1996-12-09
修稿时间:1997-03-31

Inhibitive Action of Benzotriazole for SCC of 18-8 Stainless Steel
Niu Lin, Lin Haichao, Cao Chu-nan,Song Guangling.Inhibitive Action of Benzotriazole for SCC of 18-8 Stainless Steel[J].Acta Physico-Chimica Sinica,1997,13(9):802-807.
Authors:Niu Lin  Lin Haichao  Cao Chu-nan  Song Guangling
Institution:Institute of Corrosion and Protection of Metals,State Key Laboratory for Corrosion and Protection,The Academy of Sciences,Sehnyang 110015
Abstract:The SCC susceptibility of 1Cr18Ni9Ti austenitic stainless steel in O.5 mol.L-1 HCl 0.5mol.L-1 NaCl solutions and the inhibiting effect of benzotriazole (BTA) for SCC and general corrosion were investigated by slow strain rate technique (SSRT), polarization measurements and electrochemical impedance spectroscopy. The results indicated that the inhibitive action of BTA can be attributed to its adsorption and inhibiting effects on the anodic reaction of metal dissolution due to the blocking of the active sites on metal surface.
Keywords:1Cr18Ni9Ti austenitic stainless steel  Stress corrosion cracking susceptibility  Inhibitive action mechanism  Adsorption  Anodic dissolution
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