| 金属酞菁与咪唑类配体的轴向配位反应热力学 |
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| 引用本文： | 郭福春,陈德文,徐广智. 金属酞菁与咪唑类配体的轴向配位反应热力学[J]. 物理化学学报, 1997, 13(9): 838-842. DOI: 10.3866/PKU.WHXB19970913 |
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| 作者姓名： | 郭福春 陈德文 徐广智 |
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| 作者单位： | Institute of Chemistry,Academia Sinica,Beijing 100080 |
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| 摘 要： |
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| 关 键 词： | 金属酞菁 咪唑 热力学 轴向配位 |
| 收稿时间： | 1996-12-25 |
| 修稿时间： | 1997-04-10 |
Study on the Thermodynamics of Axial Coordination Reaction of Iron-Phthalocyanine with Imidazoles |
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| Guo Fu-Chun,Chen De-Wen,Xu Guang-Zhi. Study on the Thermodynamics of Axial Coordination Reaction of Iron-Phthalocyanine with Imidazoles[J]. Acta Physico-Chimica Sinica, 1997, 13(9): 838-842. DOI: 10.3866/PKU.WHXB19970913 |
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| Authors: | Guo Fu-Chun Chen De-Wen Xu Guang-Zhi |
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| Affiliation: | Institute of Chemistry,Academia Sinica,Beijing 100080 |
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| Abstract: | The thermodynamics of axial coordination reactions of Fe-phthalocyanine with various ligands of imidazoles in DMF solution has been studied. The axial coordination number(n)and equilibrium constants (βn) of the coordinating reaction were determined by spectral techniques. The steric and electrionic effects of the axial ligands were compared. The influence of temperature on the coordination reactions was discussed. The difference of axial coordinations of metallo-phthalocyanine and metallo-porphyrin with imidazoles was also analyzed. |
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| Keywords: | Metallo-phthalocyanine Imidazole Thermodynamics Axial coordination |
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