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助剂钾添加方式对多乙苯脱氢催化性能的影响
引用本文:宋蔚,梁珍成,秦永宁. 助剂钾添加方式对多乙苯脱氢催化性能的影响[J]. 物理化学学报, 1997, 13(1): 79-82. DOI: 10.3866/PKU.WHXB19970117
作者姓名:宋蔚  梁珍成  秦永宁
作者单位:College of Tianjin Chemical Engineering,Tianjin 300402,Department of Chemical Engineering of Tianjin University,Tianjin 300072
摘    要:

关 键 词:脱氢催化剂  钾霞石  反应活性  多乙苯  
收稿时间:1996-04-11
修稿时间:1996-10-20

Influence of the Method of Adding Potassium Promoter on Catalyst for Dehydrogenation of Diethylbenzene
Song Wei,Liang Zhen-Cheng,Qin Yong-Ning. Influence of the Method of Adding Potassium Promoter on Catalyst for Dehydrogenation of Diethylbenzene[J]. Acta Physico-Chimica Sinica, 1997, 13(1): 79-82. DOI: 10.3866/PKU.WHXB19970117
Authors:Song Wei  Liang Zhen-Cheng  Qin Yong-Ning
Affiliation:College of Tianjin Chemical Engineering,Tianjin 300402|Department of Chemical Engineering of Tianjin University,Tianjin 300072
Abstract:The catalyst for dehydrogenation of diethylbenzene(DEB) to divinylbenzene(DVB) was studied. Potassium-promoted iron oxide catalyst was mainly used for ethylbenzene dehydrogenation. If potassium alkli or salt was used directly as promoter, it was noted that the loss of potassium component from the surface of the catalysts pellet result in deactivation. When potassium promoter was added as kaliophilite(KAlSiO4). It was shown that the latter way of adding potassium promoter not only keeps the depression of carbonaceous deposits but also controls the loss of potassium component(the value of loss of potassium component has been reduced three times) , thus making the catalyst having a higher dehydrogention activity.
Keywords:Dehydrogenation catalyst   Kaliophilite   Reactivity   Diethylbenzene
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