The N-N stretching band of hydrazine |
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Authors: | Iwona Gulaczyk Alain Valentin |
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Affiliation: | a Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań PL 60-780, Poland b Laboratoire de Physique Moléculaire et Applications (CNRS UMR 7092), Université Pierre et Marie Curie, VI, 4 Place Jussieu, Tour 13, Case 76, F-75252 Paris Cedex 05, France |
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Abstract: | For the first time a very weak N-N stretching band (ν5) of hydrazine was unambiguously assigned in the Fourier-transform infrared spectrum. Almost 1500 transitions with a resolution of for K′ from 0 to 6 and for all symmetry species have been analyzed. Despite some perturbations a global fit has been carried out successfully and the band center was determined at , much higher than previously expected. |
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