Kinetic regularities of conversion of ozone complexes with arenes |
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| Authors: | E. V. Avzyanova N. N. Kabal'nova V. V. Shereshovets |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | The kinetic regularities of conversion of ozone complexes with several substituted benzenes (ArX = C6H5Me, C6H5Et, C6H5CHMe2, C6H5CMe3, C6H5F, C6H5Cl,m-BrC6H5Me, and C6H5CH2Cl) were studied by spectrophotometry. The rate of consumption of [ArX · O3 in a CH2Cl2-ArX solution obeys the kinetic equationW =k0[ArX · O3]+k1 [ArX · O3][ArX]. The values of the rate constants ko andk1for the complexes studied were determined at -60+0 °C.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 371–374, 'February, 1996. |
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| Keywords: | ozone aromatic hydrocarbons ozone complexes reaction mechanism rate constants ozonolysis |
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