A solvent-free, SeCN-/(SeCN)3- based ionic liquid electrolyte for high-efficiency dye-sensitized nanocrystalline solar cells |
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| Authors: | Wang Peng Zakeeruddin Shaik M Moser Jacques-E Humphry-Baker Robin Grätzel Michael |
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| Affiliation: | Laboratory for Photonics & Interfaces, Swiss Federal Institute of Technology, CH 1015 Lausanne, Switzerland. |
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| Abstract: | A solvent-free ionic liquid electrolyte based on the SeCN-/(SeCN)3- redox couple has been employed for high-efficiency dye-sensitized nanocrystalline solar cells. For the first time an alternative redox couple has been identified to rival and even exceed the performance of the iodide/triiodide couple even at full sunlight. Unprecedented 7.5-8.3% power conversion efficiencies under AM 1.5 sunlight have been achieved for photovoltaic devices with solvent-free ionic liquid electrolytes. |
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