Synchronized adiabatic decoupling |
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Authors: | Zhang S Gorenstein D G |
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Institution: | Sealy Center for Structural Biology, University of Texas Medical Branch, Galveston, Texas, 77555-1157, USA. |
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Abstract: | A new decoupling scheme termed "synchronized adiabatic decoupling" is developed for use in the indirectly detected dimension. After each increment, the decoupling sequence is replaced by another one with different period T or different initial period T(ini) so that sampling always occurs at the end of a complete decoupling period. The effects of J coupling are therefore completely averaged out for all data points. As a result, all decoupling sidebands disappear and the center band increases correspondingly. Since the synchronized adiabatic decoupling does not require conventional editing techniques to cancel the sidebands, it is useful in high-field gradient-enhanced multidimensional experiments with only a single scan per increment. |
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