Reaction of methyl-substituted pyrylium salts with tertiary amines |
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Authors: | É. A. Zvezdina M. P. Zhdanova V. A. Bren G. N. Dorofeenko |
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Affiliation: | (1) Scientific-Research Institute of Physical and Organic Chemistry, Scientific-Research Institute of Biology, Rostov State University, Rostov-on-Don |
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Abstract: | 2,4,6-Trimethylpyrylium perchlorate reacts with heterocyclic compounds containing apyridine nitrogen atom and having basicities higher than 9 pKa units (in acetonitrile) through a step involving the formation of a methylenepyran. 4-Methyl-2,6-diphenyl- and 2-methyl-4,6-diphenylpyrylium perchlorates react with benzimidazole to give 1,2-ethanediylidenebispyrans. Methyl-substituted pyrylium salts react with 2,6-diphenylpyrylium and flavylium perchlorates in the presence of benzimidazole to give methylidynecyanines and with acetic anhydride to give trimethylidynecyanines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1484–1489, November, 1976. |
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