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A facile and efficient Bi(III) catalyzed synthesis of 1,1-dihydroperoxides and 1,2,4,5-tetraoxanes
Authors:Koneni V Sashidhara  Srinivasa Rao AvulaL Ravithej Singh  Gopala Reddy Palnati
Institution:Medicinal and Process Chemistry Division, CSIR-Central Drug Research Institute, Lucknow 226 001, India
Abstract:Bismuth triflate is a remarkably efficient and mild catalyst for the synthesis of both 1,1-dihydroperoxides and 1,2,4,5-tetraoxanes. The successful application of this methodology for the synthesis of both symmetrical and unsymmetrical tetraoxanes is demonstrated.
Keywords:Synthesis  Dihydroperoxides  Tetraoxanes  Bi(III) catalyst
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