|
|||||
|
|
| 聚（3，4-二氯）噻吩的制备及表征 | |
| 引用本文： | 李会敏,高永建,郭威,关祥瑞.聚（3，4-二氯）噻吩的制备及表征[J].化学研究,2009,20(2):76-78. |
| 作者姓名： | 李会敏 高永建 郭威 关祥瑞 |
| 作者单位： | 1. 海军后勤技术装备研究所,北京,100072 2. 北京大学化学与分子工程学院,北京,100871 3. 防化研究院,北京,102205 |
| 摘 要： | 以四氯噻吩为原料，采用化学合成法制备了聚（3，4-二氯）噻吩．对影响合成材料结构规整度的溶剂极性进行了初步探讨，并采用元素分析、红外光谱、^13C NMR核磁谱等对目标产物进行了表征．结果表明，当采用极性较低的乙二醇二甲醚作溶剂时，可得到规整度较高的目标产物． |
| 关 键 词： | 聚噻吩 四氯噻吩 聚(3 4-二氯)噻吩 导电聚合物 |
Sythesis and Characterization of Poly(3,4-dichloro)thiophene |
|
| LI Hui-min,GAO Yong-jian,GUO Wei,GUAN Xiang-rui.Sythesis and Characterization of Poly(3,4-dichloro)thiophene[J].Chemical Research,2009,20(2):76-78. | |
| Authors: | LI Hui-min GAO Yong-jian GUO Wei GUAN Xiang-rui |
| Institution: | LI Hui-min, GAO Yong-jian, GUO Wei, GUAN Xiang-rui ( 1. Institute of Naval Logistical Technology and Equipment, Beijing 100072, China; 2. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China; 3. Research Institute of Chemical Defence, Beijing 102205, China) |
| Abstract: | Poly(3,4-dichloro)thiophene was synthesized in order to get light conducting polymer with ideal properties.The π-conjugated structure of the prepared polymer is related to the polar of solvent,so different polar solvents were investigated.The characterizations of poly(3,4-dichloro)thiophene were performed by elemental analysis,IR spectrum,13C NMR and TGA. |
| Keywords: | polythiophene tetrachlorothiophene poly(3 4-dichloro)thiophene conductive polymer |
| 本文献已被 维普 万方数据 等数据库收录！ | |