A novel enantioselective (2Z)-alk-2-enylation of aldehydes via an allyl-transfer reaction from chiral allyl donors prepared from (+)-isomenthone |
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| Authors: | Nokami Junzo Nomiyama Kenta Shafi Siddiqi M Kataoka Kazuhide |
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| Affiliation: | Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700-0005, Japan. nogami@dac.ous.ac.jp |
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| Abstract: | A highly enantioselective (2Z)-alk-2-enylation of aldehydes was successfully achieved by an allyl-transfer reaction from a chiral allyl donor, which was easily obtained by separation of a diastereomeric mixture of the corresponding homoallylic alcohol gamma-adducts derived from (+)-isomenthone with alk-2-enylmagnesium chloride. [reaction: see text] |
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