The enantioselective total synthesis of a beta-carboline alkaloid, (S)-(-)-dichotomine C |
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Authors: | Omura Kana Choshi Tominari Watanabe Shiroh Satoh Yuhsuke Nobuhiro Junko Hibino Satoshi |
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Institution: | Graduate School of Pharmacy and Pharmaceutical Sciences, Faculty of Pharmacy and Pharmaceutical Sciences, Fukuyama University, Fukuyama, Hiroshima, Japan. |
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Abstract: | The first enantioselective synthesis of a beta-carboline alkaloid, dichotomine C, possessing antiallergic effects, was achieved by constructing a beta-carboline framework based on the microwave-assisted thermal electrocyclic reaction of a 1-azahexatriene system, followed by the Sharpless asymmetric dihydroxylation. |
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