Zeolite-supported rhodium complexes and clusters: switching catalytic selectivity by controlling structures of essentially molecular species |
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| Authors: | Serna Pedro Gates B C |
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| Affiliation: | Department of Chemical Engineering and Materials Science, University of California, One Shields Avenue, Davis, California 95616, USA. |
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| Abstract: | Precise synthesis and characterization of site-isolated rhodium complexes and extremely small rhodium clusters supported on zeolite HY allow control of the catalyst selectivity in the conversion of ethene to n-butene or ethane, respectively, as a result of tuning the structure of the active sites at a molecular level. |
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