| 水催化脱卤反应:构建每次一个水分子的纳米化学反应体系(英文) |
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| 引用本文： | D. L. Phillips C. Zhao W. M. Kwok Y.L. Li X. Guan D. Wang. 水催化脱卤反应:构建每次一个水分子的纳米化学反应体系(英文)[J]. 光散射学报, 2005, 17(3): 251-253 |
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| 作者姓名： | D. L. Phillips C. Zhao W. M. Kwok Y.L. Li X. Guan D. Wang |
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| 作者单位： | Department of Chemistry，The University of Hong Kong，Pokfulam Road，Hong Kong S.A.R.，China，Department of Chemistry，The University of Hong Kong，Pokfulam Road，Hong Kong S.A.R.，China |
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| 摘 要： | pacc:8240,8760E Acombinedexperimentalandtheoretical studyofthephotochemistryofCHBr3inpurewa terandinacetonitrile/watermixedsolventsisre portedthatelucidatesthereactionsandmecha nismsresponsibleforthephotochemicalconver sionofthehalogenatomsinCHBr3intothre…
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| 关 键 词： | 水催化 脱卤反应 水分子 纳米化学反应体系 光化学 卤素元素 |
| 文章编号： | 1004-5929（2005）03-0251-03 |
Water-catalyzed Dehalogenation Reactions: Building a Nanoscale Chemical Reaction System One Water Molecule at a Time |
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| D.L.Phillips,C.Zhao,W.M.Kwok,Y.L.Li,X.Guan,D.Wang. Water-catalyzed Dehalogenation Reactions: Building a Nanoscale Chemical Reaction System One Water Molecule at a Time[J]. Chinese Journal of Light Scattering, 2005, 17(3): 251-253 |
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| Authors: | D.L.Phillips C.Zhao W.M.Kwok Y.L.Li X.Guan D.Wang |
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| Abstract: | A combined experimental and theoretical study of the photochemistry of CHBr3 in pure water and in acetonitrile/water mixed solvents is reported that elucidates the reactions and mechanisms responsible for the photochemical conversion of the halogen atoms in CHBr3 into three bromide ions in water solution. |
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