Polyborane reactions in ionic liquids: new efficient routes to functionalized decaborane and o-carborane clusters |
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| Authors: | Kusari Upal Li Yuqi Bradley Mark G Sneddon Larry G |
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| Affiliation: | Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA. |
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| Abstract: | In contrast to reactions that have been observed in traditional organic solvents, decaborane olefin-hydroboration and alkyne-insertion reactions have been found to proceed in ionic liquid solvents without the need of a catalyst. These reactions now provide important new, high-yield synthetic pathways to functionalized decaborane and o-carborane clusters. |
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