原煤和黑液水煤浆燃烧特性的热分析对比研究

在热天平上进行黑液水煤浆和原煤的燃烧、热解实验，得到不同升温速率下的燃烧、热解特性曲线和碳转化率特征曲线。试验结果表明，黑液水煤浆中的钠及其化合物在燃烧过程中催化作用明显，并且黑液中有机物成分对燃烧起到一定促进作用。在20 ℃/min升温速率下黑液水煤浆和原煤的燃烧活化能分别为12.98 kJ/mol和106.59 kJ/mol，反映出黑液水煤浆比原煤有更好的着火特性。

Thermal analysis on combustibility of coal and coal black liquor slurry

Pyrolysis and combustibility of coal and coal black liquor slurry were studied on the thermobalance. The characteristics of pyrolysis, combustion and carbon conversion are all obtained under different heating rates . It is shown that the combustion of coal black liquor slurry is catalyzed by sodium and its compound ,and also the organic matter composition plays a certain role in the burning of coal black liquor slurry. The activation energy of coal and coal black liquor slurry combustion at the heating rate of 20 ℃/min are 12.98 kJ/mol and 106.59 kJ/mol, respectively ，which indicates that the combustion characteristic of coal black liquor slurry is better than that of coal.