| 钴希夫碱配合物的合成及其氧合机制的研究——Ⅰ.配合物及其氧加合物的合成和表征 |
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| 引用本文： | 韩志坚,周洪,陈汉文,戴寰.钴希夫碱配合物的合成及其氧合机制的研究——Ⅰ.配合物及其氧加合物的合成和表征[J].无机化学学报,1992(4). |
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| 作者姓名： | 韩志坚 周洪 陈汉文 戴寰 |
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| 作者单位： | 南京大学化学系，南京大学化学系，南京大学化学系，南京大学化学系 南京 210008，南京 210008，南京 210008，南京 210008 |
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| 摘 要： | 本文合成了一系列以水杨醛或萘酚醛同多胺缩合的四齿(N_2O_2)或五齿(N_3O_2)希夫碱为配体的钴希夫碱配合物及它们的氧加合物,用元素分析、红外光谱、磁化率以及ESR谱进行了表征,在续篇中将继续讨论配合物的吸氧行为和氧合机制。
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| 关 键 词： | 希夫碱 配合物 钴 分子氧加合物 |
STUDIES ON SYNTHESIS AND OXYGENATION MECHANISM OF COBALT SCHIFF BASE COMPLEXES I. SYNTHESES AND CHARACTERIZATION OF COMPLEXES AND THEIR CARRYING OXYGEN ADDUCTS |
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| Han Zhijian Zhou Hong Chen Hanwen Dai Huan.STUDIES ON SYNTHESIS AND OXYGENATION MECHANISM OF COBALT SCHIFF BASE COMPLEXES I. SYNTHESES AND CHARACTERIZATION OF COMPLEXES AND THEIR CARRYING OXYGEN ADDUCTS[J].Chinese Journal of Inorganic Chemistry,1992(4). |
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| Authors: | Han Zhijian Zhou Hong Chen Hanwen Dai Huan |
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| Abstract: | A scries of cobalt (II) complexes of non-planner tetra-dentatc(N2O2) or penta-dentate (N3O2) Schiff-basc ligands derived from salicylaldehydc or naphthylaldehyde and polyaminc, and their oxygen adducts have been synthesized. These complexes and their oxygen adducts were characterized by elemental analysis, IR spectra, magnetic susceptibility and ESR measurement. The behavior and mechanism of the oxygcnation of complexes will be discussed further. |
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| Keywords: | Schiff base complex cobalt molecular oxygen adduct |
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