| Sulfamic Acid as a Cost-effective Catalyst for Acetolysis of Cyclic Ethers |
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| 引用本文： | WeiZhongGONG BoWANG YahLongGU LiangYAN LiMingYANG JiShuanSUO. Sulfamic Acid as a Cost-effective Catalyst for Acetolysis of Cyclic Ethers[J]. 中国化学快报, 2005, 16(6): 747-750 |
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| 作者姓名： | WeiZhongGONG BoWANG YahLongGU LiangYAN LiMingYANG JiShuanSUO |
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| 作者单位： | [1]StateKeyLaboratoryforOxoSynthesisandSelectiveOxidation,LanzhouInstituteofChemicalPhysics,ChineseAcademyofSciences,Lanzhou730000／／InstituteofBiologyofGansuAcademyofsciences,Lanzhou730000 [2]StateKeyLaboratoryforOxoSynthesisandSelectiveOxidation,LanzhouInstituteofChemicalPhysics,ChineseAcademyofSciences,Lanzhou730000 [3]StateKeyLaboratoryforOxoSynthesisandSelectiveOxidation,LanzhouInstituteofChemicalPhysics,ChineseAcademyofSciences,Lanzhou730000／／ChengduOrganicChemicalsCo.Ltd.,ChineseAcademyofSciences,Chengdu610000 |
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| 摘 要： | Sulfamic acid has been used as an efficient catalyst and green alternative for conventional acidic materials to promote the acetolysis reaction of THF to produce 1,4-diacetoxybutane. This method is also applicable in the acetolysis of other cyclic ethers, such as methyl substituted THF and tetrahydropyran and 1,4-dioxane which is less reactivity.
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| 关 键 词： | 乙酰解 环醚 酸催化 离子性液体 |
Sulfamic Acid as a Cost-effective Catalyst for Acetolysis of Cyclic Ethers |
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| Wei Zhong GONG,,Bo WANG,Yan Long GU,Liang YAN,Li Ming YANG,Ji Shuan SUO,? State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou Institute of Biology of Gansu Academy of sciences,Lanzhou Chengdu Organic Chemicals Co. Ltd.,Chinese Academy of Sciences,Chengdu. Sulfamic Acid as a Cost-effective Catalyst for Acetolysis of Cyclic Ethers[J]. Chinese Chemical Letters, 2005, 16(6): 747-750 |
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| Authors: | Wei Zhong GONG Bo WANG Yan Long GU Liang YAN Li Ming YANG Ji Shuan SUO ? State Key Laboratory for Oxo Synthesis Selective Oxidation Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou Institute of Biology of Gansu Academy of sciences Lanzhou Chengdu Organic Chemicals Co. Ltd. Chinese Academy of Sciences Chengdu |
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| Affiliation: | Wei Zhong GONG1,2,Bo WANG1,Yan Long GU1,Liang YAN1,Li Ming YANG1,Ji Shuan SUO1,3? 1 State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000 2 Institute of Biology of Gansu Academy of sciences,Lanzhou 730000 3 Chengdu Organic Chemicals Co. Ltd.,Chinese Academy of Sciences,Chengdu 610000 |
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| Abstract: | Sulfamic acid has been used as an efficient catalyst and green alternative for conventional acidic materials to promote the acetolysis reaction of THF to produce 1, 4-diacetoxybutane. This method is also applicable in the acetolysis of other cyclic ethers, such as methyl substituted THF and tetrahydropyran and 1,4-dioxane which is less reactivity. |
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| Keywords: | Sulfamic acid acetolysis cyclic ether acid catalysis ionic liquid. |
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