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Electrolytic synthesis of ammonia in molten salts under atmospheric pressure
Authors:Murakami Tsuyoshi  Nishikiori Tokujiro  Nohira Toshiyuki  Ito Yasuhiko
Affiliation:Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University, Sakyo-ku, Japan.
Abstract:Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber-Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodically oxidized and reacts with hydrogen to produce ammonia at the anode.
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