Metal-directed formation of three-dimensional M(3)L(2) trigonal-bipyramidal cages |
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| Authors: | Radhakrishnan U Schweiger M Stang P J |
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| Affiliation: | Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA. |
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| Abstract: | [reaction: see text] The simple combination of two angular tritopic pyridine donor linkers (109 degrees bond angle) with three ditopic platinum acceptors (90 degrees bond angle) leads to essentially quantitative formation of self-assembled M(3)L(2) trigonal-bipyramidal (TBP) supramolecular species. |
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