Synthesis and Crystal Structure of a Novel Mixed Ligand Cadmium(II) Complex of Benz-1,3-Thiazoline-2-Thione and 1,10-Phenanthroline |
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| Authors: | A. Tadjarodi F. Adhami Z. Gharehdaghi G. Kickelbick |
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| Affiliation: | (1) College of Chemistry, Iran University of Science & Technology (IUST), Daneshgah St., Hengam St., Resalat SQ, 16846 Tehran, Iran;(2) Islamic Azad University, Shahr-Rey Branch, Tehran, Iran;(3) Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9, 1060 Vienna, Austria |
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| Abstract: | Abstract A novel cadmium complex [Cd(C7H4NS2)2(phen)] was synthesized by the reaction of a polymeric complex, [Cd(C7H4NS2)2] n , with 1,10-phenanthroline (phen) as a ligand. The crystal structure was determined by single-crystal X-ray diffraction. The crystallographic data are: triclinic  , a = 8.3670(6) ?, b = 10.9898(8) ?, c = 17.1404(13) ?, α = 95.567(2)o, β = 95.881(2)o, γ = 109.034(1)o, V = 1471.26(19) ?3 and Z = 2. The final R value is 0.0375 for 7154 reflections. The compound [Cd(C7H4NS2)2(phen)] is monomeric revealing a coordination sphere of N4S2 type. The Cd atom is surrounded by two thiazole N atoms, two exocyclic S atoms from two bidentate 1,3-benzothiazole-2-thiolate anions and two 1,10-phenanthroline N atoms. The Cd cation is six-coordinate with a distorted octahedral geometry. Graphical Abstract The synthesis and crystal structure of a novel monomeric complex ‘[Cd(C7H4NS2)2(phen)]’ obtained by the reaction of polymeric complex, [Cd(C7H4NS2)2] n , with 1,10-phenanthroline is reported.  |
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| Keywords: | Benz-1,3-thiazoline-2-thione 1,10-Phenanthroline Crystal structure Cadmium complex |
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