"Governing initiation-supporting termination" in chiral poly(n-hexyl isocyanate) |
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| Authors: | Shah Priyank N Min Joonkeun Lee Jae-Suk |
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| Institution: | Department of Nanobio Materials and Electronics and School of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagiro (1 Oryong-dong), Buk-gu, Gwangju 500712, Republic of Korea. |
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| Abstract: | Poly(n-hexyl isocyanate) (PHIC) with varying molecular weights were synthesized using a chiral initiator and chiral terminator by living anionic polymerization. In such PHICs, chirality of the initiator plays a decisive role in determining the helical sense of the entire polymeric chain, whereas chirality of the terminator plays a supportive role. |
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