A four coordinate parent imide via a titanium nitridyl |
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| Authors: | Tran Ba L Washington Marlena P Henckel Danielle A Gao Xinfeng Park Hyunsoo Pink Maren Mindiola Daniel J |
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| Affiliation: | Indiana University, 800 E. Kirkwood Avenue, Bloomington, Indiana, USA. |
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| Abstract: | Treatment of d(1) [(nacnac)TiCl(Ntol(2))] with NaN(3) results in NaCl formation and N(2) ejection to yield the first four coordinate, parent imide [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=[ArNC(CH(3))](2)CH, Ar = 2,6-iPr(2)C(6)H(3), tol = 4-CH(3)C(6)H(4)). |
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